ACADSTAFF UGM
| Title | : | Amino-functionalized porous chitosan as a solid base catalyst for solvent-free synthesis of chalcones |
| Author | : |
HERNAWAN (1) Prof. Drs. Bambang Purwono, M.Sc., Ph.D. (2) Prof. Dr. Triyono, S.U. (3) Muhammad Hanafi (4) |
| Date | : | 26 2022 |
| Keyword | : | amino-functionalized,porous chitosan,chalcones amino-functionalized,porous chitosan,chalcones |
| Abstract | : | Background: The introduction of heterogeneous catalysts from biomass enables new opportunities for the development of heterogeneous base-organocatalysts for various organic syntheses. Among them, amino-functionalized porous chitosan with high specific surface area has promising properties but its use as a base catalyst in chalcone synthesis is still rarely reported. Methods: Amino-functionalized porous chitosan as a solid base catalyst was fabricated from porous chitosan grafted with aminopropyltriethoxysilane (APTMS). The prepared hybrid materials were characterized with pore and specific surface area (N2-sorption), FTIR, SEM, and accessible amine. Significant Findings: The results reveal that the amount of APTMS had a significant effect on the physicochemical properties of amino-functionalized porous chitosan catalysts. The hybrid materials were employed as a solid base catalyst for solvent-free synthesis of chalcones. The catalyst offered good yield synthesis, lower temperature, less reaction time, highly selective, stable, recoverable, and can be reused four times without significant loss in performance. |
| Group of Knowledge | : | Kimia |
| Original Language | : | English |
| Level | : | Internasional |
| Status | : |
Published
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