ACADSTAFF UGM

CREATION
Title : Modification of Mordenite Characteristics by H2C2O2 and/or NaOH Treatments and Its Catalytic Activity Test in Hydrotreating of Pyrolyzed Cellulose
Author :

Prof. Dr. Triyono, S.U. (1) Prof. Dra. Wega Trisunaryanti, M.S., Ph.D.,Eng. (2) YESSI WYDIA PUTRI (3) DYAH AYU FATMAWATI (4) USWATUL CHASANAH (5)
Date : 17 2021
Keyword : H2C2O4 treatment; NaOH treatment; ?-cellulose hydrotreating; mordenite; mesoporous structure H2C2O4 treatment; NaOH treatment; ?-cellulose hydrotreating; mordenite; mesoporous structure
Abstract : The research about modification of mordenite characteristics has been performed by H2C2O4 and/or NaOH treatments and catalytic activity tests in hydrotreating of pyrolyzed ?-cellulose. Commercial mordenite (HSZ-604OA) as mordenite control (HM) immersed in 0.05, 0.5, and 1.0 M H2C2O4 at 70 °C for three hours resulting in HM-0.05, HM-0.5, and HM-1. The four mordenites were immersed in 0.1 M NaOH for 15 minutes resulting in BHM, BHM-0.05, BHM-0.5, and BHM-1. The catalysts obtained were analyzed by XRD, SAA, ICP, and acidity test. The catalytic activity of the mordenites was evaluated in hydrotreating of pyrolyzed ?-cellulose using stainless steel reactor with an H2 gas flow rate of 20 mL.min?1 at 450 °C for two hours with a catalyst: feed weight ratio of 1:60. The liquid products obtained from the hydrotreating were analyzed using GC-MS. The research results showed that the H2C2O4 and/or NaOH treatment towards the mordenites increased Si/Al ratio and decreased crystallinity. The acidity of mordenites decreased along with the increase of the Si/Al ratio. The average pore diameter of BHM, BHM-0.05, BHM-0.5, and BHM-1 mordenites were 2.898; 3.005; 3.792; 7.429 nm, respectively. The BHM-0.5 mordenite showed the highest catalytic activity in generating liquid product (88.88 wt%) and selectivity toward propanol (4.87 wt%). The BHM-1 mordenite showed catalytic activity in generating liquid product (41.16 wt%) and selectivity toward ethanol (1.21 wt%) and 2-heptyne (4.36 wt%).
Group of Knowledge : Kimia
Original Language : English
Level : Internasional
Status :
Published
Document
No Title Document Type Action
1 published BCREC 16(1).pdf
Document Type : [PAK] Full Dokumen
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2 Paper-published-Jan2021-BCREC-Triyono-dkk.pdf
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3 Paper-published-Jan2021-BCREC-Triyono-dkk.pdf
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