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Title : One Step Synthesis of Symmetrical Amino Azine Derivatives Using Hydrazine Hydrate as a Reagent
Author :

NURUL HIDAYAH (1) Prof. Drs. Bambang Purwono, M.Sc., Ph.D. (2) Prof. Dr.rer.nat. Harno Dwi Pranowo, M.Si. (3)

Date : 1 2020
Keyword : Azine,Electron-Withdrawing Group, Hydrazine Hydrate Azine,Electron-Withdrawing Group, Hydrazine Hydrate
Abstract : Symmetrical Amino Azine derivative compound of 6,6'-((1E,1'E)-hydrazine-1,2-diylidenebis (methanyl-ylidene)) bis (3,4-dimethoxyaniline) TM has been synthesized through an unusual reaction route employed benzylidine derivative with some electron withdrawing groups as intermediate compounds. The targeted TM compound was prepared by one pot reaction of the intermediate 2-(4,5-dimethoxy-2-nitrobenzylidene) malononitrile 3 or (E)-1,2-dimethoxy-4-nitro-5-(2-nitrovinyl)-benzene 4 or nitrohydrazone 5 with excess 80% hydrazine hydrate and 10% Pd/C catalyst. However, direct synthesis to produce TM using nitro aryl aldehyde derivatives with 80% hydrazine hydrate and 10% Pd/C catalyst failed to obtain the target compound of TM.
Group of Knowledge : Kimia
Original Language : English
Level : Internasional
Status :
Published
Document
No Title Document Type Action
1 One Step Synthesis of Symmetrical Amino Azine Derivatives Using Hydrazine Hydrate as a Reagent.pdf
Document Type : [PAK] Full Dokumen
[PAK] Full Dokumen View
2 Nurul One Step jurnal_2077124_85525c748387f3c413b870938c8acc65.pdf
Document Type : [PAK] Cek Similarity
[PAK] Cek Similarity View