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Title : Synthesis, Characterizations and Catalysis of Sulfated Silica and Nickel Modified Silica Catalysts for Diethyl Ether (DEE) Production from Ethanol towards Renewable Energy
Author :

Prof. Dr. rer. nat. Karna Wijaya, M.Eng. (1) MELYNATRI LAURA (2) Maisari Utami (3) Dr. Dra. Sri Mulijani, MSi (4) Aep Patah, S.Si., M.Si., Ph.D. (5) Arief Cahyo Wibowo (6) Prof. Dr. Murugesan Chandrasekaran (7) Prof. Dr. Jothi Ramalingam Rajabathar (8) Hamad Al-Lohedan (9)
Date : 11 2021
Keyword : Sulfated silica,Catalyst,Nanoparticle,Diethyl ether,Fuel additives,Ethanol Sulfated silica,Catalyst,Nanoparticle,Diethyl ether,Fuel additives,Ethanol
Abstract : Sulfated silica (SO4/SiO2) and nickel impregnated sulfated silica (Ni-SO4/SiO2) catalysts have been successfully carried out for the conversion of ethanol into diethyl ether (DEE) as a biofuel. The aims of this research were to study the effects of acidity on the SO4/SiO2 and Ni-SO4/SiO2 catalysts in the conversion of ethanol into diethyl ether. This study focuses on the increases in activity and selectivity of SiO2 with the impregnation of sulfate and Ni metal, which had good activity and acidity and were less expensive. The SO4/SiO2 catalysts were prepared using TEOS (Tetraethyl Orthosilicate) as a precursor and sulfuric acid with various concentrations (1, 2, 3, 4 M). The results showed that SO4/SiO2 acid catalyst treated with 2 M H2SO4 and calcined at 400 C (SS-2-400) was the catalyst with highest total acidity (2.87 g/mmol), while the impregnation of Ni metal showed the highest acidity value at 3%/Ni-SS-2 catalyst (4.89 g/mmol). The SS-2-400 and 3%/Ni-SS-2 catalysts were selected and applied in the ethanol dehydration process into diethyl ether at temperatures 175, 200, and 225 C. The activity and selectivity of SS-2-400 and 3%/Ni-SS-2 catalysts shown the conversion of ethanol reached up to 9.54% with good selectivity towards diethyl ether liquid product formation.
Group of Knowledge : Kimia
Original Language : English
Level : Internasional
Status :
Published
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1 catalysts-11-01511.pdf
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2 catalysts-11-01511.pdf
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