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Title : Synthesis of high stability Mo/SiO2 catalyst utilizing Parangtritis beach sand for hydrocracking waste palm oil into biofuel
Author :

GESHA DESY ALISHA (1) Prof. Dra. Wega Trisunaryanti, M.S., Ph.D.,Eng. (2) Akhmad Syoufian, Ph.D. (3) SAVITRI LARASATI (4)

Date : 6 2021
Keyword : Molybdenum,Hydrocracking,Biofuel,Amorphous silica,Catalyst Molybdenum,Hydrocracking,Biofuel,Amorphous silica,Catalyst
Abstract : In this work, the optimum condition for hydrocracking waste palm oil (WPO) over Mo/SiO2 catalyst was studied in order to obtain biofuel with high level hydrocarbon. Natural source Parangtritis beach sand was utilized to provide amorphous silica support for preparing Mo/SiO2 hydrocracking catalyst via wet impregnation in fve diferent Mo concentrations: 1.22 wt%, 4.50 wt%, 4.66 wt%, 5.74 wt%, 7.63 wt%, and each is labelled as Mo(A)/SiO2, Mo(B)/SiO2, Mo(C)/SiO2, Mo(D)/ SiO2, and Mo(E)/SiO2, respectively. With the use of amorphous SiO2, two MoO3 structures, α-MoO3 and h-MoO3, were found in catalysts comprising Mo≥4 wt% in XRD analysis. This study shows that at 550 °C with 1:300 catalyst:feed ratio, Mo(C)/SiO2, which possesses the highest total acidity among the others (1.71 mmol/g), exhibits an excellent hydrocracking performance by producing over 87 wt% liquid conversion containing 94 wt% hydrocarbon compounds. Moreover, the reusability of Mo(C)/SiO2 was found to be efective for 5 hydrocracking runs before it started to show a declining conversion level. Regeneration of Mo(C)/SiO2 was surprisingly able to recover its initial performance by producing 75.78 wt% liquid product containing 90.03 wt% hydrocarbon in the hydrocracking of WPO.
Group of Knowledge : Kimia
Original Language : English
Level : Internasional
Status :
Published
Document
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1 Paper-published-BCAB-Q2-Nov2021-Geshadkk-Synthesis-pdf.pdf
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2 Paper-published-BCAB-Q2-Nov2021-korespondensi.pdf
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3 Synthesis of high stability Mo-SiO2 catalyst utilizing Parangtritis beach sand for hydrocracking waste palm oil into biofuel.pdf
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