ACADSTAFF UGM

CREATION
Title : Synthesis of Symmetrical Acetophenone Azine Derivatives as Colorimetric and Fluorescent Cyanide Chemosensors
Author :

NUR MASYITTAH IRMI (1) Prof. Drs. Bambang Purwono, M.Sc., Ph.D. (2) Prof. Dr. Chairil Anwar (3)

Date : 8 2021
Keyword : acethophenone,azine,colorimetry,fluorescents,cyanide acethophenone,azine,colorimetry,fluorescents,cyanide
Abstract : Cyanide is a highly toxic anion and poison to the environment. Therefore, fast, effective, and efficient analysis methods to detect cyanide are needed. Herein, symmetrical chemosensor of 2’-hydroxy acetophenone azine (1) and 2’,4’-dihydroxy acetophenone azine (2) has been synthesized tested as colorimetric and fluorescent cyanide chemosensor. The azines were produced from the condensation of acetophenone derivatives with hydrazine hydrate in ethanol under reflux or ultrasonic irradiation methods. Colorimetric and fluorescent chemosensor tests showed selectivity to acetate and cyanide anions in DMSO. The limit of detection (LOD) for colorimetric measurement of cyanide anion was 9.68×10–4 M for compound (1) and 9.63×10–5 M for compound (2), while the fluorescent method showed 15.90×10–4 M for compound (1) and 8.95×10–5 M for compound (2), respectively. In addition, test paper-strips containing sensor 2 indicated noticeable results for 'naked eye' detection of cyanide in an aqueous medium.
Group of Knowledge : Kimia
Original Language : English
Level : Internasional
Status :
Published
Document
No Title Document Type Action
1 2021-Nur Masyittah-IJC.pdf
Document Type : [PAK] Full Dokumen
[PAK] Full Dokumen View
2 Synthesis of Symmetrical Acetophenone Azine Derivatives as Colorimetric and Fluorescent Cyanide Chemosensors.pdf
Document Type : [PAK] Cek Similarity
[PAK] Cek Similarity View
3 Bukti korespondensi.pdf
Document Type : [PAK] Bukti Korespondensi Penulis
[PAK] Bukti Korespondensi Penulis View