ACADSTAFF UGM

CREATION
Title : The efective combination of zirconia superacid and zirconia‑impregnated CaO in biodiesel manufacturing: Utilization of used coconut cooking oil (UCCO)
Author :

Erlin Purwita Sari (1) Prof. Dr. rer. nat. Karna Wijaya, M.Eng. (2) Prof. Dra. Wega Trisunaryanti, M.S., Ph.D.,Eng. (3) Akhmad Syoufian, Ph.D. (4) Hasanudin (5) WAHYU DITA SAPUTRI (6)
Date : 23 2021
Keyword : Biodiesel, Esterifcation,Transesterifcation,Acid–base catalyst, Used coconut cooking oil Biodiesel, Esterifcation,Transesterifcation,Acid–base catalyst, Used coconut cooking oil
Abstract : The present study reports the efective combination of zirconia superacid and zirconia-impregnated CaO in biodiesel manufacturing through the utilization of used coconut cooking oil. The acid catalyst was synthesized by the wet impregnation method combined with H2SO4 0.9 M. This mixture was calcined at 500 °C and yielding the highest catalyst acidity of 3.60 mmol g−1. The free fatty acid (FFA) levels of UCCO then was reduced through the esterifcation process by varying the catalyst weight, UCCO-to-methanol mole ratio, calcination temperature, and reaction time. Optimum FFA level was achieved with 5% catalyst weight, 1:15 UCCO/methanol ratio, and 1.5 h reaction time with reduced FFA level to 0.42%. The Zr–CaO catalyst was synthesized using the refux method through heating at 80 °C for 4 h, achieving the highest catalyst basicity, 27.78 mmol g−1, at a condition of 1% (w/w) Zr–CaO and calcination temperature of 800 °C. This catalyst was then used in the transesterifcation reaction to produce biodiesel. Transesterifcation reaction was carried out by 5% catalyst weight and esterifcation product to methanol mole ratio of 1:20 for 1.5 h, yielding a conversion value of UCCO into biodiesel of 55.35%.
Group of Knowledge : Kimia
Original Language : English
Level : Internasional
Status :
Published
Document
No Title Document Type Action
1 Sari2021_Article_TheEffectiveCombinationOfZirco.pdf
Document Type : Bukti Published
Bukti Published View
2 Sari2021_Article_TheEffectiveCombinationOfZirco.pdf
Document Type : Bukti Published
Bukti Published View
3 Universitas Gadjah Mada Mail - Your Submission IJEE-D-21-00343R1 - [EMID_ad8106184f23c5f9].pdf
Document Type : [PAK] Bukti Korespondensi Penulis
[PAK] Bukti Korespondensi Penulis View
4 jurnal_erlin_turnitin.pdf
Document Type : [PAK] Full Dokumen
[PAK] Full Dokumen View
5 erlin_artikel_turnitin.pdf
Document Type : [PAK] Cek Similarity
[PAK] Cek Similarity View